Freeman离子源的特性与改进研究

此文简要叙述用于离子束材料改性装置的Ｆｒｅｅｍａｎ离子源的特性，其主要参数：灯丝电流、孤压、磁场、气流量和吸极电压与引出离子束流强的关系。对源体内部因微漏冷却水（真空度由３．９×１０－４降至４．２×１０－４Ｐａ）致使气体分子电离、起弧困难和等离子体不稳作了实验研究；对灯丝与弧室间的氮化硼绝绝物上沉积被溅射出的Ｗ、Ｍｏ原子导致绝缘下降、灯丝寿命缩短进行了部份结构改进。结果表明，提高加工工艺，确保真空系统密封性能和输入气体纯度对弧室内气体分子碰撞电离和等离子体的稳定至关重要；在ＢＮ绝缘物上放置钼制屏蔽罩有效地屏蔽掉Ｗ、ＭＯ原子沉积使灯丝寿命延长一倍，达到了４０小时。     

抑制性消减杂交方法的建立

为建立研究基因表达差异的抑制性消减杂交（SSH）方法，以未加诱导剂处理的结肠癌LoVo细胞提取的mRNA为模板合成的cDNA作为驱赶子（driver)，联合使用10.0μmol/LATRA和0.1μmol/L1,25-(OH)2D3诱导2d的LoVo细胞提取的mRNA为模板合成的cDNA作为测试子（tester)进行SSH实验，结果为：消减产物与未消减样品（对照）在琼脂糖凝胶电泳图谱上明显不同，前者可见一些扩增条带，其大小范围在100-1000bp之间，本实验说明SSH方法对于识别差异表达的基因具有高效性。     

Cross-talk Noise Suppresion in Volume Holography with a Composite Reading Beam

ＣｒｏｓｔａｌｋＮｏｉｓｅＳｕｐｐｒｅｓｉｏｎｉｎＶｏｌｕｍｅＨｏｌｏｇｒａｐｈｙｗｉｔｈａＣｏｍｐｏｓｉｔｅＲｅａｄｉｎｇＢｅａｍＬＩＸｉａｏｃｈｕｎＷＵＭｉｎｘｉａｎＨＥＱｉｎｇｓｈｅｎｇＪＩＮＧｕｏｆａｎ（ＤｅｐａｒｔｍｅｎｔｏｆＰｒｅｃｉ...     

Determination of ionization constants of saccharides by capillary zone electrophoresis with amperometric detection

Summary A method based on a linear model enabling the efficient determination of the ionization constants (K _a) of saccharides by capillary zone electrophoresis with amperometric detection has been demonstrated. TheK _a values obtained from the plots of the reciprocal effective mobility against the inverse concentration of sodium hydroxide were in agreement with literature values.     

胶子遮蔽和末态作用对p—A碰撞中粲偶素和b夸克偶素产额压低的贡献

本文用胶子结构函数的遮蔽效应和末态作用分析了在ｐ－Ａ碰撞中粲偶素和ｂ夸克偶素产额压低的实验数据，较好地描述了粲偶素和ｂ夸克偶素产额的压低与Ａ和Ｘ２的关系．     

Rugate光学薄膜通带内反射次峰的抑制

本文探讨了抑制Rugate光学薄膜通带内反射次峰的各种方法。以五次函数匹配和正弦调制相结合的方法获得了在宽光谱范围内能很好抑制反射次峰并能保持其截止带反射率的Rugate膜系。     

Study of Structures and Electronic Properties of Pdn–1Pb and Pdn （n≤8） Clusters

Geometric and electronic properties of Pdn–1Pb and Pdn (n≤8) clusters have been studied by using density functional theory with effective core potentials, focusing on the differences between mono- and bimetallic clusters. The average bond length of Pdn–1Pb (n≤8) bimetallic clusters is longer than that of pure palladium clusters except for n = 2 and 3. The most stable structure of Pdn–1Pb (n≤7) is the singlet where there is at least a Pd or Pb atom on its excited state. The energy gaps of Pd–Pb binary clusters are narrower than those of Pdn clusters, and then the chemical activity is strengthened when Pdn clusters are doped with Pb.     

Direct calculation of ionization potentials of closed-shell atoms and molecules

Vertical ionization potentials, electron affinities and information about quasi-particles can be obtained by using the technique of the single-particle propagator. The expansion of the self-energy part up to third order perturbation theory can be evaluated numerically, but does not lead, in most cases, to satisfying results. A theoretical and numerical analysis of the diagrammatic expansion of the self-energy part requires the introduction of a renormalized interaction and renormalized hole and particle lines.     

烷烃电离能和生成焓的相关性

根据化合物形成过程中价电子能量变化与生成焓之间的关系, 推导出烷烃的生成焓和电离能之间的关系. 以21个烷烃化合物为模型将实验测定的电离能与标准生成焓进行直接关联, 证实了模型方程的适用性, 所得回归方程的相关系数达到0.9999, 估算值与实验值之间的标准偏差仅为0.03 eV. 同时还利用实验测定的标准生成焓对一系列烷烃的电离能作了预测.     

N-取代吩噻嗪和DDQ的电荷转移络合作用

具有盼嘤酸化学结构的化合物有广泛的用途I‘－＼其中吩嘤埃衍生物在医学上用作抗精神病药物特别受到药理学家们的注意，发现其药理作用与其分子提供电子的能力有关卜‘」但是我们应该注意到，作为抗精神病药物的吩嚷嚷衍生物，其吩座爆分子的氮原子都连有一个叔胺基链问，例如氯丙障（I）和奋乃静（11）．而我们知道，胺类特别是叔胺类有强的提供电子的能力＊；在上述的药物分子中是主要的提供电子因素，因此以这类化合物作为给体研究其供电子能力，是不能实际反映吩嘤嗓分子本身的给电子能力的．吩嘤噪类属于二苯并杂环化合物，分子中既…